If the partial molar volumes of the two components of a binary solution are VA 30 m2/mol and Vg 20 m3/mol and the mole fraction of component A is 0.4, find the molar volume of the solution.

Respuesta :

Answer : The molar volume of the solution is, [tex]24m^3/mole[/tex]

Explanation : Given,

Partial molar volumes of component A = [tex]30m^3/mole[/tex]

Partial molar volumes of component B = [tex]20m^3/mole[/tex]

Mole fraction of component A = 0.4

First we have to calculate the mole fraction of component B.

As we know that,

[tex]\text{Mole fraction of component A}+\text{Mole fraction of component B}=1[/tex]

[tex]\text{Mole fraction of component B}=1-0.4=0.6[/tex]

Now we have to calculate the molar volume of the solution.

Expression used :

[tex]V_s=X_A\times \bar V_A+X_B\times \bar V_B[/tex]

where,

[tex]\bar V_A[/tex] = partial molar volumes of component A

[tex]\bar V_B[/tex] = partial molar volumes of component B

[tex]V_s[/tex] =  molar volume of the solution

[tex]X_A[/tex] = mole fraction of of component A

[tex]X_B[/tex] = mole fraction of of component B

Now put all the give values in the above expression, we get:

[tex]V_s=0.4\times 30m^3/mole+0.6\times 20m^3/mole[/tex]

[tex]V_s=24m^3/mole[/tex]

Therefore, the molar volume of the solution is, [tex]24m^3/mole[/tex]

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